The rearranged ions undergo fragmentation, the predominat loss being ethene, and only a small contribution from loss of carbon monoxide is observed. Citations are the number of other articles citing this article, calculated by Crossref and updated daily. the Altmetric Attention Score and how the score is calculated. Olmstead. A Density Functional Study of the Claisen Rearrangement of Allyl Aryl Ether, Allyl Arylamine, Allyl Aryl Thio Ether, and a Series of Meta-Substituted Molecules through Reactivity and Selectivity Profiles. Versuche mit14C, 4. Mitteilung. Zemfira A. Bredikhina, Alexey V. Kurenkov, Dmitry B. Krivolapov, Alexander A. Bredikhin. You’ve supercharged your research process with ACS and Mendeley! You have to login with your ACS ID befor you can login with your Mendeley account. the Altmetric Attention Score and how the score is calculated. The wittig reaction: Stereoselectivity and a history of mechanistic ideas (1953–1995). Learn about our remote access options, Royal Society Research Unit, University College of Swansea, Singleton Park, Swansea SA2 8PP, UK, Department of Pharmacology, University of Texas, Health Science Centre, Houston, Texas 77025, USA, Faculté des Sciences, Université de l'Etat à Mons, 19 Avenue Maistriau, Mons 7000, Belgium. The first reported Claisen rearrangement is the [3,3]-sigmatropic rearrangement of an allyl phenyl ether to intermediate 1, which quickly tautomerizes to an ortho-substituted phenol. Note: Collision‐induced dissociation spectra are used to verify the structures of the daughter ions. Zur Kenntnis derClaisen-Umlagerung II. Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. Find more information on the Altmetric Attention Score and how the score is calculated. S. Kirk Wright,, Michael S. DeClue,, Ajay Mandal,, Lac Lee,, Olaf Wiest,, W. Wallace Cleland, and. Zur Kenntnis der Matthew P. Meyer,, Albert J. DelMonte, and. Stereoselective crystallization of 3-(2,6-dimethylphenoxy)propane-1,2-diol: preparation of the single-enantiomer drug mexiletine. The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Investigation into the Mechanism of Phenolic Couplings during the Biosynthesis of Glycopeptide Antibiotics. Über den Mechanismus der para-Claisen-Umlagerung. The present work is aimed to develop a me thod for allylation of phenol on Armenian natural zeolites as catalysts. Your Mendeley pairing has expired. Nematic Solvents as Media for the Claisen Rearrangement. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Get article recommendations from ACS based on references in your Mendeley library. Claisen rearrangement of allyl phenyl ether: heavy-atom kinetic isotope effects and bond orders in the transition structure. Molecular protonated ions of allyl phenyl ether undergo a Claisen rearrangement both in the ion source and along the flight path. SHINE. (Versuche mit14C, 3. Volker Hessel, Elnaz Shahbazali, Timothy Noël, Sergei Zelentsov. Note: Araceli G. Campaña, Armando Carlone, Kai Chen, David T. F. Dryden, David A. Leigh, Urszula Lewandowska, Kathleen M. Mullen. Kiran Rao, Ruchi Tyagi, Navjeet Kaur, D. Kishore. The reaction is given below – Claisen rearrangement belongs to ‘sigmatropic rearrangement’ class of reactions. One experiment that it is used for is the Claisen rearrangement . Structure-Reactivity Relationships in Homogeneous Gas-Phase Reactions: Thermolyses and Rearrangements. You have to login with your ACS ID befor you can login with your Mendeley account. Kataryna Bretosh, Sandrine Vincendeau, Lucie Routaboul, Jean-Claude Daran, Zoia Voitenko, Eric Manoury. Please note: If you switch to a different device, you may be asked to login again with only your ACS ID. In lieu of an abstract, this is the article's first page. Theoretical and experimental studies of the 3-aza-Claisen rearrangement. Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. Wenhua Ou, Sandraliz Espinosa, Héctor J. Meléndez, Silvia M. Farré, Jaime L. Alvarez, Valerie Torres, Ileanne Martínez, Kiara M. Santiago, and Margarita Ortiz-Marciales . You’ve supercharged your research process with ACS and Mendeley! catalyst. Richard H. Schlosberg, Paul F. Szajowski, Gerald D. Dupre, Jeffrey A. Danik, Argo Kurs, Terrence R. Ashe, William Im. Zur Kenntnis der Claisen-Umlagerung VI. If you do not receive an email within 10 minutes, your email address may not be registered, ChemInform Abstract: The Claisen Rearrangement of Allyl Phenyl Ether: Heavy-Atom Kinetic Isotope Effects and Bond Orders in the Transition Structure.. and you may need to create a new Wiley Online Library account. Highly regioselective O-allylation of phenol derivatives using MMZ Symposium über die Verwendung von Isotopen in der Chemie und Biochemie. The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. SAUNDERS, H. J. -Umlagerung. Enter your email address below and we will send you your username, If the address matches an existing account you will receive an email with instructions to retrieve your username, I have read and accept the Wiley Online Library Terms and Conditions of Use. This article is cited by Unlimited viewing of the article PDF and any associated supplements and figures. Find more information about Crossref citation counts. Please note: If you switch to a different device, you may be asked to login again with only your ACS ID. Claisen Rearrangement (aromatic) of Aryl Allyl Ether or Allyl Phenyl Ether – In claisen rearrangement allyl phenyl ether is converted into its aromatic enol form by rearrangement. DOI: 10.1021/jp020437o. Die Anwendung von Isotopen in der organischen Chemie.
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