You’ve supercharged your research process with ACS and Mendeley! . Ab initio static and metadynamics investigations of the Wittig reaction. One-Pot, Tandem Wittig Hydrogenation: Formal C(sp Chem. 0000009561 00000 n Get article recommendations from ACS based on references in your Mendeley library. Chem. Number of times cited according to CrossRef: Activation of Chiral (Salen)TiCl Dedicated to Professor Georg Wittig on the occassion of his 80th birthday. Acta. Roland Appel, Robert Loos and Herbert Mayr . Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. For permission to reproduce, republish and Graziano Baccolini, Camilla Delpivo, Gabriele Micheletti. Cite this paper as: Pommer H., Thieme P.C. This Microreview takes a critical look at its recent use in the total synthesis of natural heterocyclic compounds but also in the synthesis of natural heterocyclic analogues. 0 0000009239 00000 n 0000005656 00000 n Guilong Cheng,, Gholam A. Mirafzal, and. DOI: 10.1002/9780470147146.ch1. Nürrenbach, A. et al. 0000009915 00000 n Chim. 1,247,299 (1968), University of Lodz (2000495008) - Polish Consortium ICM University of Warsaw (3000169041) - Polish Consortium ICM University of Warsaw (3003616166). A Direct Route to C-Vinylaziridines: Reaction of N-Sufonylimines with Allylic Ylides under Phase-Transfer Conditions or with Preformed Ylides at Low Temperature. 0000141394 00000 n Appl., 729, 439 (1944), Van Dorp, D. A., Arens, J. F.: Rec. 5,748 (1978), Widmer, E. et al. Erika A. Crane, Thomas P. Zabawa, Rebecca L. Farmer, Karl A. Scheidt. 1,112,072 (1959), Hoffmann-La Roche (Inventors H. Stoller, H. P. Wagner), DAS 2,439,860 (1973), Hoffmann-La Roche (Inventors M. Lalonde, H. Stoller), DAS 2,548,883 (1975), BASF AG (Inventors M. Fischer, W. Wiersdorf, A. Nürrenbach, D. Horn, F. Feichtmayer), DAS 2,210,800 (1972). Recent advances in the annulation of Morita–Baylis–Hillman adducts. The literature of heterocyclic chemistry, part XVIII, 2018. 0000022800 00000 n Post-Polymerization Modification of Ring Opening Metathesis Polymerization (ROMP)-Derived Materials Using Wittig Reactions. 0000015051 00000 n 0000011038 00000 n The Wittig reaction is a well‐established approach with recognized efficiency and some stereoselectivity. Olefin metathesis has been used on an industrial scale for several decades to react non-functionalized alkenes. 0000007102 00000 n The large diversity of high‐yielding and stereoselective reactions that can be achieved, even for highly functionalized molecules, is presented, demonstrating that the Wittig reaction is an efficient and attractive strategy in synthetic organic chemistry. Role of aggregates, mixed aggregates, monomers, and free ions on the rates and selectivities of N-alkylation and E2 elimination. BASF AG (Inventors H. Freyschlag, W. Reif, A. Nürrenbach, H. Pommer), DAS 1,216,962 (1964), 1,211,616 (1963), BASF AG (Inventors H. Freyschlag, W. Reif, A. Nürrenbach, W. Sarnecki) Germ. xڬSMLQ����������R 0000005427 00000 n 0000017707 00000 n Based on an address delivered on the occasion of Prof. Wittig's 80th birthday. Marco Appel, Steffen Blaurock, Stefan Berger. The principles of the reaction will be briefly presented and discussed, but the focus will be on the most recent reports using this reaction in the synthesis of heterocyclic compounds. Diastereoselective syntheses of (Z)- and (E)-3-styrylquinolin-4(1H)-ones. Anomalous Horner-Wadsworth-Emmons reactions on 3,4-enuloses. 2 Organophosphane-Promoted Synthesis of Functionalized α,β-Unsaturated Alkenes and Furanones via Direct β-Acylation. A Novel Type of Olefin Formation. Applications of Wittig Reaction in the Total Synthesis of Natural Macrolides. Pat. Jaap C. Hanekamp, Rob Boer Rookhuizen, Hendrik J.T. Symp. Bruce E. Maryanoff, Allen B. Reitz, David W. Graden, Harold R. Almond. The Wittig reaction enables the synthesis of an alkene from the reaction of an aldehyde or ketone with the ylide generated from a phosphonium salt. %PDF-1.7 %���� The E/Z selectivity in gas phase Wittig reaction of non-stabilized, semi-stabilized and stabilized Me 3 P and Ph 3 P phosphorus ylides with monocyclic ketone: A computational study. Special Issue: 20th Anniversary (Celebrating the Past, Present and Future). Structural and Spectroscopic Evidence for the Occurrence ofgauche-Betaine Intermediates in the Thio Wittig Reaction. 0000007343 00000 n 0000022339 00000 n Retrosynthetic Analysis of the Compounds with One Functional Group. Please reconnect. not otherwise permitted to reproduce, republish, redistribute, or sell any Supporting Information Detection and Reaction of Oxaphosphetanes Derived from Benzaldehyde and 1-Adamantylmethylidene Ylide. Z 0000012792 00000 n 0000010176 00000 n 0000007262 00000 n -Halobenzophenones with Various Wittig Reagents. Raquel S. G. R. Seixas, Artur M. S. Silva, Ibon Alkorta, José Elguero. Working off-campus? Pat. 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